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Suppression of tunneling two-level systems in ultrastable glasses of indomethacin

机译:在超稳定玻璃中抑制隧道两级系统   吲哚美辛

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摘要

Glasses and other non-crystalline solids exhibit thermal and acousticproperties at low temperatures anomalously different from those found incrystalline solids, and with a remarkable degree of universality. Below a fewK, these universal properties have been successfully interpreted using theTunneling Model, which has enjoyed (almost) unanimous recognition for decades.Here we present low-temperature specific-heat measurements of ultrastableglasses of indomethacin that clearly show the disappearance of the ubiquitouslinear contribution traditionally ascribed to the existence of tunnelingtwo-level systems (TLS). When the ultrastable thin-film sample is thermallyconverted into a conventional glass, the material recovers a typical amount ofTLS. This remarkable suppression of the TLS found in ultrastable glasses ofindomethacin is argued to be due to their particular anisotropic and layeredcharacter, which strongly influences the dynamical network and may hinderisotropic interactions among low-energy defects, rather than to thethermodynamic stabilization itself. This explanation may lend support to thecriticisms by Leggett and others to the standard Tunneling Model, although moreexperiments in different kinds of ultrastable glasses are needed to ascertainthis hypothesis.
机译:玻璃和其他非结晶固体在低温下表现出的热和声学特性与在结晶固体中发现的异常不同,并且具有显着的通用性。几K以下,这些通用性质已使用隧道模型成功解释,该模型已经(几乎)获得了数十年的一致认可。在这里,我们介绍了吲哚美辛超稳定玻璃的低温比热测量,清楚地表明了传统上普遍存在的线性贡献的消失归因于存在隧道二级系统(TLS)。当将超稳定的薄膜样品热转化为常规玻璃时,该材料可回收典型量的TLS。据认为,在吲哚美辛超稳定玻璃中发现的TLS的这种显着抑制是由于它们独特的各向异性和层状特征,它强烈影响动力学网络并可能阻碍低能缺陷之间的各向异性相互作用,而不是热力学稳定性本身。尽管需要更多不同种类的超稳定玻璃的实验来确定这一假设,但这种解释可能会为Leggett和其他人对标准隧道模型的批评提供支持。

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